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P2NP reductive amination by Zeb - Mon, 20 Feb 2017 15:02:04 EST ID:F56IS3nI No.78536 Ignore Report Quick Reply
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where can i find the true procedure to reduce P2NP to the amine with hgcl2/al?
>>
Jack Blackdock - Sat, 15 Apr 2017 23:52:51 EST ID:fXXYn8yb No.78638 Ignore Report Quick Reply
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>>78536
funny story i tried this route many times with poor results, that amalgam is a bitch and/or not strong enough to reduce the molecule OR I fucked up something doing the amalgamation process

somebody has experience with this procedure?
>>
Fuck Drasslewill - Sun, 23 Apr 2017 17:51:32 EST ID:F7xhKEnl No.78642 Ignore Report Quick Reply
>>78638
bamping
>>
Nell Blindlewater - Sun, 14 May 2017 17:03:04 EST ID:dJ2q6ECJ No.78652 Ignore Report Quick Reply
>>78638
nobody?
>>
Bombastus !uYErosQbLM!!Mybq1UbK - Sun, 14 May 2017 23:10:56 EST ID:3RVckahy No.78653 Ignore Report Quick Reply
>>78638
uhhhhh
>>
press - Tue, 16 May 2017 17:59:40 EST ID:OHYz+LTM No.78654 Ignore Report Quick Reply
>>78638
ime Eleusis was partly correct in hi quotation of vogels.
if you prepare the aluminium in advance it tends to get the job done much quicker and ... well quicker and thus much more dangerously. you should always care for proper safety precautions converning spillage when dealing with highly toxic bullshit.
>>
Archie Bungerworth - Fri, 02 Jun 2017 15:20:38 EST ID:buvhlIwH No.78675 Ignore Report Quick Reply
>>78654
just how high are you?
>>
press - Tue, 06 Jun 2017 05:18:01 EST ID:xjn9cxbO No.78676 Ignore Report Quick Reply
1496740681851.jpg -(24215B / 23.65KB, 636x319) Thumbnail displayed, click image for full size.
>>78675
a strong six out of ten, id guess.
------------------------------------------------------

The Proper Preparation of Aluminum Amalgam
by Eleusis

This is for all of you Dr. Shulgin fans out there that might be a little miffed at poor yields when attempting mild reductive aminations (not the fruity little Disney characters, kids). The trick here is *cleaning* the damned foil before you use it. Follow closely, be careful with the mercuric solutions, they can be absorbed transdermally (in other words, use gloves, dumbass).
Preparation of Aluminum Amalgam

Aluminum Amalgam is a useful mild reducing agent which requires careful preparation in order to be effective. The following is adapted from Vogel's Practical Organic Chemistry.

Prepare 10% Sodium Hydroxide solution by dissolving 20g NaOH in 180mL of distilled water.

Prepare a ~2% Mercuric (II) Chloride solution by dissolving 1g of HgCl2 in 50mL of distilled water.

Cut 40g of aluminum foil into small squares approximately .5cm a side.

Place the aluminum into a large beaker or other suitable glass container and cover with the sodium hydroxide solution. Heat gently in a well ventilated area until hydrogen gas evolves vigorously for about 3 minutes. Strain the foil through a plastic colander and wash first with distilled water, then with denatured alcohol. Pat dry then add to a beaker with the 2% HgCl2 solution. Allow to amalgamate for 2 minutes then pour off the supernatant. It is unethical to pour mercury compounds down the drain, but you'll probably do it anyway ;-). Now wash the foil in the colander as before, with distilled water, ethanol, and then a little bit of ether. Submerge the aluminum amalgam in ether to store until use.

>>
Nicholas Dunningbut - Wed, 14 Jun 2017 19:49:28 EST ID:ZYvGRZ+j No.78689 Ignore Report Quick Reply
>>78676
tbh I prefer to use something more direct and efective to reduce chemicals
>>
Bombastus !uYErosQbLM!!Mybq1UbK - Wed, 14 Jun 2017 23:45:52 EST ID:Pues0B4h No.78690 Ignore Report Quick Reply
>>78689
LiAlH under nitrogen. But then again, that's completely different...


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